An Access database is just a shared file, it's not an active DB server. There is no command to kick users from Access itself. To kick people out, you have to use the file sharing services on the server to close the user's file.
On the server, go to Administrative tools -> Computer management. On the left pane, open to Shared Folders, then click Open Files. You should see each person who has the mdb file open. From there you can forcibly close the file for each user.
Remember, this can cause missed updates if the a user is suddenly terminated before writes are flushed. Use this with care.
If you are having trouble with multiple users, it's time to move to a real multi-user database system. For example, you can buy SQL server or use the free and open source MySQL. Either system allows multiple users to see the data on the server and you can do things like live backups and force people off without losing data.
You can use Access as a front end, to display forms and reports while storing the data on the backend server. This way if you forcibly close the file, you are not screwing with your data store.
Since people are not closing the Access file, I can just about guarantee you are not getting backups of your database, which is dangerous. Access is good for trying things out and for a single user system and can be used occasionally for a couple of simultaneous users. It's purpose and design is not for a 24/7 multi-user database.